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About Programmed Temperature Vaporising (PTV)
Introduction
Temperature programmed sample introduction was first described by Vogt in 1979. Originally Vogt developed the technique
as a method for the introduction of large sample volumes (up to 250 µL) in capillary GC. Vogt introduced the sample into
the liner at a controlled injection rate. The temperature of the liner was chosen slightly below the boiling point of the solvent.
The low-boiling solvent was continuously evaporated and vented through the split line. Based on this idea Poy developed
the Programmed Temperature Vaporising injector; PTV. By introducing the sample at a low initial liner temperature many
of the disadvantages of the classical hot injection techniques could be circumvented. Nowadays PTV injection is generally
considered to be the most universal injection technique available.
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